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We identify a ferroelectric topological structure, termed "dipole spiral," which exhibits a giant intrinsic piezoelectric response (>320 pC/N). This helical structure, primarily stabilized by entro…
Here, using first-principles calculations on PbTiO3 under biaxial tensile strain, we unveil a novel form of polar order: a chiral, non-collinear ferroelectric double helix. We find that the Pb- and…